Chem Chapter 15

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Energy

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43 Terms

1

Energy

The capacity to do work or produce heat; exists as potential energy and kinetic energy.

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2

Potential Energy

Energy that is stored in an object due to its composition or position.

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3

Kinetic Energy

Energy of motion

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4

Law of Conservation of Energy

States that in any chemical reaction or physical process, energy may change from one form to another, but it is neither created or destroyed.

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5

Chemical Potential energy

The energy stored in a substance because of its composition; most is absorbed or released as heat during chemical reactions or processes

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6

Heat

A form of energy that flows form a warmer object to a cooler object

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7

calorie

The amount of heat required to raise the temperature of one gram of pure water by one degree Celsius

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8

Joule

The SI unit of heat and energy

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9

Specific heat

The amount of heat required to raise the temperature by one gram of a given substance by one degree Celsius

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10

Calorimeter

An insulated device that is used to measure the amount of heat released or absorbed during a physical or chemical process

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11

Thermochemistry

The study of heat changes that accompany reactions and phase changes.

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12

System

In thermochemistry, the specific part of the universe containing the reaction or process being studied

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13

Surroundings

In thermochemistry, includes everything in the universe except for the system.

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14

Enthalpy

The heat content of a system at constant pressure. (H)

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15

Equation involving Enthalpy

Enthalpy of Reaction=Final Enthalpy-Initial Enthalpy

or

Enthalpy of reaction=Product Empathy-Reactant enthalpy

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16

Enthalpy changes for _________ reactions are always negative

exothermic

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17

Endothermic

Energy is absorbed by the chemical reaction

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18

Exothermic

Energy is released by the chemical reaction

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19

Enthalpy changes for _______ reactions are always positive

endothermic

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20

Thermochemical equation

A balanced chemical equation that includes the physical states of all the reactants and the energy change, usually expressed as the change in enthalpy.

(Basically a balanced chemical equation)

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21

Enthalpy of combustion

The enthalpy change for the complete burning of one mole of a given substance.

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22

Molar enthalpy of fusion

The amount of heat required to melt one mole of a solid substance.

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23

Molar enthalpy of vaporization

The amount of heat required to vaporize one mole of a solid substance

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24

Molar Enthalpy of vaporization=

negative (-) molar enthalpy of condensation

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25

Molar enthalpy of fusion=

negative (-) molar enthalpy of solidification

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26

Combustion

The reaction of a fuel with oxygen

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27

Hess’s Law

States that if two or more thermochemical equations can be added to produce a final equation for a reaction, then the sum of the enthalpy changes for the individual reactions is the enthalpy change for the final reaction.

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28

standard enthalpy of formation

The change in enthalpy that accompanies the formation of one mole of a compound in its standard state from its constituent elements in their standard series.

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29

Spontaneous process

A physical or chemical change that occurs without outside intervention and may require energy to be supplied to begin the process.

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30

Entropy (s)

A measure of the number of possible ways that the energy of a system can be distributed; related to the freedom of the system’s particles to move and the number of ways they can be arranged.

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31

Second law of thermodynamics

The spontaneous processes always proceed in such a way that the entropy of the universe increases

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32

Heating Curve

What happens to a substance as it is heated

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33

1 Joule in calories

0.239 calories

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34

1 calorie in joules

4.184 Joules

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35

1 CALORIE in kilocalories

1 kilocalorie

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36

1 CALORIE in calories

1000 calories

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37

variable “q”

heat absorbed/released (In joules)

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38

variable “m”

Mass of sample (in grams)

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39

variable “c”

Specific heat of the substance (J/gC) (C=Celsius)

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40

variable “t”

the change in temperature (in Celsius) (T final- T initial)

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41

Calculating heat equation

q= M x C x T

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42

The SI Unit of heat and energy

Joule

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43

The specific heat value that heats up the Fastest……

Is the smallest number and vice verse. Water is the slowest to heat up with its specific heat at 4.185

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