molecule
2 or more chemical elements make up a molecule
smallest unit of a substance that retains chemical & physical properties of the substance
organic molecule
carbon-based; carbon atoms typically bonded together
intramolecular forces
forces within a molecule
types of intramolecular forces
ionic
polar covalent
non-polar covalent
covalent bond
forms when valence electrons of 2 non-metal atoms are shared so that both may have a full valence shell
electronegativity
ability of an atom to attract electrons stronger to other atoms (e.g oxygen, nitrogen, chlorine)
dipole
a bond or molecule whose ends have opposite charges
ionic
when a metal loses electrons and non-metal gains the electrons
cation - positive ion (metal)
anion - negative ion (non-metal)
non-polar covalent
covalent bond w/ electrons being shared equally, both atoms do not possess a positive or negative charge
polar covalent
covalent bond w/ electrons being attracted to the atom of higher electronegativity (making it slightly more negative and the other atom slightly more positive)
intermolecular forces
forces between molecules or between different parts of a molecule (if it’s large enough)
weaker than intramolecular forces
hydrogen bond
atom of a molecule being attracted to an atom of another molecule due to differing polarity
e.g positive hydrogen atom of a water molecule being attracted to negative oxygen atom of a water molecule
hydrophobic effect
tendency of non-polar molecules to clump together in substances
hydrophobic interaction
non-polar molecules are unable to form hydrogen bonds with other polar molecules
hydrophilic interaction
polar molecules are able to form hydrogen bonds w/ water molecules
ions
an atom or group of atoms that loses or gains an electron to obtain a stable valence shell
has an electrical charge
cation
an atom that has lost an electron
positively charged
anion
an atom that has gained an electron
negatively charged
molecular formula
shows the # of each type of atom in an element or compound
e.g C6H12O6
structural formula
a diagram of a molecule that shows how atoms of the molecule are bonded together
lines drawn between atoms indicate covalent bonds
biochemical reaction
normally involves a combination of more than one
4 main chemical reactions biological molecules undergo
neutralization
oxidation-reduction
condensation
hydrolysis
acid
substance that produces hydrogen ions (H^+) when it dissolves in water
increases concentration of ions in an aqueous solution
base
substance that produces hydroxide ions when it (OH^-) when it dissolves in water
increases concentration of hydroxide ions
can be thought of as a substance that accepts or reacts with hydrogen ions
pH scale
ranking of substances according to the relative concentration of their hydrogen ions
neutralization
acid-base reaction
acid interacts w/ a base resulting in salt (ionic compound) & water
both acid & base lose their acidic & base properties respectively
buffers
substances that minimize changes in pH by donating or accepting hydrogen ions as needed
oxidation
when a molecule loses an electron & becomes oxidized
reduction
when a molecule accepts electrons from an oxidized molecule
oxidation-reduction
oxidation & reduction occurs at the same time so the whole reaction is termed this
redox reaction
condensation
hydrogen is removed from a functional group on one molecule
an OH group is removed from another molecule
the 2 molecules bond and form a larger molecule & water
all 4 types of biological macromolecules involve this reaction between the monomers of each polymer
hydrolysis
breaks down macromolecules into monomers in cells
hydrogen from water is added to one monomer
an OH group is added to another monomer beside it
covalent bond between these 2 monomers breaks & the larger molecule is split into 2 smaller molecules
isomer
a molecule with the same molecular formula but different structure
monomer
molecule that can bond to other identical molecules to form a polymer
polymer
molecule made of multiple monomers
4 main types of macromolecules
carbohydrates
lipids
proteins
nucleic acid
carbohydrates
contains carbon, hydrogen and oxygen
easy-to-access energy
polar; soluble in water
e.g sugar & starches
types of carbohydrates
monosaccharide
disaccharide
polysaccharide
glycosidic linkage
covalent bond b/w 2 monosaccharides
forms b/w specific hydroxyl groups on each mono saccharide
hexose
6 carbon sugar
A glucose, B glucose, galactose, fructose
pentose
5 carbon sugar
ribose, deoxyribose
monosaccharide
composed of a single carbon-based monomer
a monomer for other carbohydrates
A glucose, B glucose, galactose, fructose
disaccharide
2 monosaccharides covalently bonded
maltose, sucrose, lactose
polysaccharide
monosaccharides joined together by glycosidic linkage
starch, glycogen, cellulose