Orbitals
a region in an atom where there is a high probability of finding electrons
energy level
a region of an atom in which electrons of the same energy are likely to be found
amount of electrons in s orbital
2 electrons in orbital
amount of electrons in p orbital
6 electrons in orbital
amount of electrons on d orbital
10 electrons in orbital
amount of electrons in f orbital
14 electrons in orbital
amount of electrons in g orbital
18 electrons in orbital
Poly exclusion principle
no two electrons in the same atom can have the same set of four quantum numbers
ground state
The lowest energy state of an atom
excited state
A state in which an atom has more energy than it does at its ground state, going to a higher energy level
ground state and excited state- nitrogen
G: 1s^2 2s^2 2p^3 E:1s^2 2s^2 2p^2 3s^1
Aufbau Principle
An electron occupies the lowest-energy orbital that can receive it
hund's rule
single occupancy of orbital before pairing
Pauli Exclusion Principle
An atomic orbital may describe at most two electrons, each with opposite spin direction
valence electrons
Electrons on the outermost energy level of an atom
shielding electrons
electrons in the energy levels between the nucleus and the valence electrons
atomic radius
size of an atom
atomic radius trend
increases down a group, decreases across a period
atomic radius increases
down because of more energy levels meaning more shielding electrons
atomic radius decreases
across because of effective nuclear charge increases
Ionisation energy
The energy required to the remove an electron from the outer shell of an atom.
ionization energy trend
increases up and to the right
Electronegativity
the ability of an atom to attract electrons when the atom is in a compound
electronegativity trend
increases up and to the right
first ionization energy
the energy required to remove the first electron from an atom
ionization energy decrease
The outer electrons are further away from the nucleus and hence are not as tightly held
ionization energy increase
effective nuclear charge increases as electron shielding remains constant, so it is harder to take the electron
Electronegatvity decreases
The outer electrons are further away from the nucleus and hence are not as tightly held
electronegativity increase
effective nuclear charge increases as electron shielding remains constant, so it is harder to take the electron
assumed charge for transitional metals unless stated otherwise
+2
writing formula for metals
must use roman numerals
anion
A negatively charged ion
cation
A positively charged ion
octet rule
A rule that states that an atom will give up, accept, or share electrons in order to achieve a filled outer electron shell, which usually consists of 8 electrons.
polyatomic ion
A charged group of covalently bonded atoms
molecule
two or more atoms held together by covalent bonds
alloy
A mixture of two or more metals
unshared pair
pair of electrons not invovled in bonding instead by exclusively a single atom
forming a bond
stable and exothermic
breaking a bond
unstable and endothermic
ionic bond
Formed when one or more electrons are transferred from one atom to anothe
ionic bond transfer
cations (metal) to anions (salt)
ionic bond properties
high melting points, good solubility in water, poor conductors of heat and electricity in lattice and brittle
ionic lattice
repeating pattern of positive and negative ions forming an ionic compound
electrostatic repulsion
Describes a force between particles with opposite electrical charges that causes them to push apart from one another
electrostatic attraction
the attraction between positive and negative charges
polar bonds
a type of covalent bond between atoms that differ in electronegativity. the shared electrons are pulled closer to the more electronegative atom. making one slightly negative and the other slightly positive
covalent bonds
Bonds created by sharing electrons with other atoms.
double bonds
the sharing of two pairs of electrons between two atoms
polar covalent
a type of bond that forms when electrons are not shared equally
coordinate covalent bond
a covalent bond in which one atom contributes both bonding electrons
covalent network
atoms covalently bonded into a large structure that does not contain a specific number of atoms
covalent bond characteristics
-share electrons -lower melting point -lower boiling point -poor conductors
covalent network characteristics
very hard, very high melting points, poor conductors
metallic bonds
a bond formed by the attraction between positively charged metal ions and the electrons around them
delocalized electrons
electrons that are free to move in metals
metal bonds characteristics
good heat and electricity conductors in both molten and solid state, ductile, malleable, luster, high melting and boiling point
luster in metal bond
light being reflected of movement of valence electrons
polyatomic ions
A charged group of covalently bonded atoms
Mass Spectromentry
can measure the number of electrons in an area
Relative atomic mass formula
Sum of (isotope abundance x isotope mass number) / 100
saturated
onyl has single bonds
unsaturated
double or more bonds
Spectroscopy
The study of the properties of light that depend on wavelength.
light
both a particle and a wave
photons
particles of light energy that are completely weightless
Flame test
Testing chemicals by burning a compound to look at its flame color. Certain compounds and elements burn with distinctive colors.
Flame test sodium
Yellow flame
Flame test: Potassium
Lilac flame
Flame test: Lithium
Crimson flame
Flame test copper
Green flame
Flame test: Calcium
Orange-red flame
spectrometer
a device that spreads light into its different colors
light absorption
pigments absorb certain colours of light by an atom when electrons get excited by certain wavelengths and move up energy levels, the remaining colours of light are reflected
light emisison
excited electron going back down to a grounded state giving out light energy as it returns down
density
the mass relative tot he space an object takes up