Chemistry- Unit 1: Atomic Properties

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Orbitals

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76 Terms

1

Orbitals

a region in an atom where there is a high probability of finding electrons

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2

energy level

a region of an atom in which electrons of the same energy are likely to be found

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3

amount of electrons in s orbital

2 electrons in orbital

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4

amount of electrons in p orbital

6 electrons in orbital

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5

amount of electrons on d orbital

10 electrons in orbital

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6

amount of electrons in f orbital

14 electrons in orbital

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7

amount of electrons in g orbital

18 electrons in orbital

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8

Poly exclusion principle

no two electrons in the same atom can have the same set of four quantum numbers

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9

ground state

The lowest energy state of an atom

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10

excited state

A state in which an atom has more energy than it does at its ground state, going to a higher energy level

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11

ground state and excited state- nitrogen

G: 1s^2 2s^2 2p^3 E:1s^2 2s^2 2p^2 3s^1

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12

Aufbau Principle

An electron occupies the lowest-energy orbital that can receive it

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13

hund's rule

single occupancy of orbital before pairing

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14

Pauli Exclusion Principle

An atomic orbital may describe at most two electrons, each with opposite spin direction

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15

valence electrons

Electrons on the outermost energy level of an atom

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16

shielding electrons

electrons in the energy levels between the nucleus and the valence electrons

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17

atomic radius

size of an atom

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18

atomic radius trend

increases down a group, decreases across a period

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19

atomic radius increases

down because of more energy levels meaning more shielding electrons

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20

atomic radius decreases

across because of effective nuclear charge increases

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21

Ionisation energy

The energy required to the remove an electron from the outer shell of an atom.

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22

ionization energy trend

increases up and to the right

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23

Electronegativity

the ability of an atom to attract electrons when the atom is in a compound

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electronegativity trend

increases up and to the right

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first ionization energy

the energy required to remove the first electron from an atom

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26

ionization energy decrease

The outer electrons are further away from the nucleus and hence are not as tightly held

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ionization energy increase

effective nuclear charge increases as electron shielding remains constant, so it is harder to take the electron

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Electronegatvity decreases

The outer electrons are further away from the nucleus and hence are not as tightly held

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electronegativity increase

effective nuclear charge increases as electron shielding remains constant, so it is harder to take the electron

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30

assumed charge for transitional metals unless stated otherwise

+2

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31

writing formula for metals

must use roman numerals

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32

anion

A negatively charged ion

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33

cation

A positively charged ion

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34

octet rule

A rule that states that an atom will give up, accept, or share electrons in order to achieve a filled outer electron shell, which usually consists of 8 electrons.

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35

polyatomic ion

A charged group of covalently bonded atoms

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36

molecule

two or more atoms held together by covalent bonds

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alloy

A mixture of two or more metals

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38

unshared pair

pair of electrons not invovled in bonding instead by exclusively a single atom

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39

forming a bond

stable and exothermic

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40

breaking a bond

unstable and endothermic

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41

ionic bond

Formed when one or more electrons are transferred from one atom to anothe

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42

ionic bond transfer

cations (metal) to anions (salt)

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43

ionic bond properties

high melting points, good solubility in water, poor conductors of heat and electricity in lattice and brittle

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ionic lattice

repeating pattern of positive and negative ions forming an ionic compound

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electrostatic repulsion

Describes a force between particles with opposite electrical charges that causes them to push apart from one another

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electrostatic attraction

the attraction between positive and negative charges

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47

polar bonds

a type of covalent bond between atoms that differ in electronegativity. the shared electrons are pulled closer to the more electronegative atom. making one slightly negative and the other slightly positive

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48

covalent bonds

Bonds created by sharing electrons with other atoms.

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49

double bonds

the sharing of two pairs of electrons between two atoms

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50

polar covalent

a type of bond that forms when electrons are not shared equally

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coordinate covalent bond

a covalent bond in which one atom contributes both bonding electrons

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covalent network

atoms covalently bonded into a large structure that does not contain a specific number of atoms

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covalent bond characteristics

-share electrons -lower melting point -lower boiling point -poor conductors

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covalent network characteristics

very hard, very high melting points, poor conductors

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55

metallic bonds

a bond formed by the attraction between positively charged metal ions and the electrons around them

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delocalized electrons

electrons that are free to move in metals

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metal bonds characteristics

good heat and electricity conductors in both molten and solid state, ductile, malleable, luster, high melting and boiling point

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luster in metal bond

light being reflected of movement of valence electrons

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polyatomic ions

A charged group of covalently bonded atoms

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60

Mass Spectromentry

can measure the number of electrons in an area

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Relative atomic mass formula

Sum of (isotope abundance x isotope mass number) / 100

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saturated

onyl has single bonds

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unsaturated

double or more bonds

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Spectroscopy

The study of the properties of light that depend on wavelength.

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65

light

both a particle and a wave

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66

photons

particles of light energy that are completely weightless

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Flame test

Testing chemicals by burning a compound to look at its flame color. Certain compounds and elements burn with distinctive colors.

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Flame test sodium

Yellow flame

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Flame test: Potassium

Lilac flame

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70

Flame test: Lithium

Crimson flame

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Flame test copper

Green flame

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Flame test: Calcium

Orange-red flame

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73

spectrometer

a device that spreads light into its different colors

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74

light absorption

pigments absorb certain colours of light by an atom when electrons get excited by certain wavelengths and move up energy levels, the remaining colours of light are reflected

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light emisison

excited electron going back down to a grounded state giving out light energy as it returns down

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76

density

the mass relative tot he space an object takes up

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