AP Chem Chapter 9 Terms Test (11th Unit)

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hybridization

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32 Terms

1

hybridization

mixing of different types of atomic orbitals to produce a set of equivalent hybrid orbitals

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2

trigonal bipyramidal

5 bonding domains, 0 nonbonding

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3

diamagnetism

type of magnetism that causes a substance with no unpaired electrons to be weakly repelled from a magnetic field

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4

bent

2 bonding domains, 1 or 2 nonbonding

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5

angstrom

unit of metric measurement equal to 1x10-10m, often used to measure atomic distance, Å

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6

tetrahedral

4 bonding domains, 0 nonbonding

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7

molecular orbital theory

theory that accounts for the allowed states for electrons in molecules

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8

square pyramidal

5 bonding domains, 1 nonbonding

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9

VSEPR theory

a model that accounts for the geometric arrangements of shared and unshared electron pairs around a central atom in terms of the repulsions between electron pairs

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10

T-shaped

3 bonding domains, 2 nonbonding

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11

bonding molecular orbital

molecular orbital in which electron density s concentrated in the internuclear region, σ and π

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12

square planar

4 bonding domains, 2 nonbonding

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13

equatorial bond

three electron domains that come off an atom with five total domains with a bond angle of 120°

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14

trigonal pyramidal

3 bonding domains, 1 nonbonding

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15

bond order equation

(1⁄2)(MO-MO*)

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16

molecular orbital diagram

diagram that shows the energies of molecular orbitals relative to the atomic orbitals from which they are derived

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17

bonding pair

pair of electrons that are shared by two atoms

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18

pi bond

covalent bond in which electron density is concentrated above and below the line joining the bonded atoms, π bond

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19

valence-bond theory

model of chemical bonding in which an electron-pair bond is formed between two atoms by the overlap of orbitals on the two atoms

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20

trigonal planar

3 bonding domains, 0 nonbonding

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21

molecular orbital

an allowed state for an electron in a molecule, MO

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22

paramagnetism

property a substance possesses if it contains one or more unpaired electron, will be drawn into a magnetic field

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23

nonbonding pair

pair of electrons assigned completely to one atom; also called a lone pair

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24

sigma bond

covalent bond in which electron density is concentrated along the internuclear axis, σ bond

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25

octahedral

6 bonding domains, 0 nonbonding

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26

electron domain

regions around a central atom where electrons are likely to be found

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27

bond order

half the difference of the number of electrons in bonding orbitals and the number of electrons in nonbonding orbitals

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28

seesaw

4 bonding domains, 1 nonbonding

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29

antibonding molecular orbital

molecular orbital in which electron density is concentrated outside the region between the two nuclei of bonded atoms, σ* and π*

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30

axial bond

two electron domains that come off an atom with five total domains with a bond angle of 180°

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31

linear

2 bonding domains, 0 or 3 nonbonding

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32

hybrid orbital

orbital that results from the mixing of different kinds of atomic orbitals in the same atom

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